When Hester is first alone with Chillingworth, for instance, and in several preceding descriptions, she appears to be undergoing a process of destruction herself. She is immensely ashamed, and very aware of the eyes that dart furtively towards the letter emblazoned on her chest; she is too weak to think straight when Chillingworth administers a medicine to Pearl that could, for all Hester knows, be poison, and she is far too weak to resist Chillingworth's insistence that she keep his secrets.
Hester is the first of the three major characters, however, to make a transition to a stronger and more secure position with herself and with her sin; she has clearly found an inner redemption long before the others. The reason for this is the same as the reason that she is the first, and for the bulk of the book the only, character to acknowledge her sin -- Pearl....
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